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dc.contributor.authorHamzioui, Louanes-
dc.description.abstractIn this work, we studied the influence of P2O5 on the crystal structure, the microstructure and the dielectric and piezoelectric properties of a new ceramic material of the general formula: Pb0.98Ca0.02[(Zr0.52Ti0.48)0.98(Cr3+ 0.5, Ta5+ 0.5)0.02]O3 and of structure perovskite. The samples chosen for this study were prepared by a conventional oxide mixing technique. A thermal treatment was applied on these samples at different temperatures (1000, 1050, 1100, 1150 and 1180 °C). Various techniques of characterization were used for this study such as the X-ray diffraction, the scanning electron microscopy, the atomic force microscopy and electrical measurements. The results indicate that all the ceramics have a perovskite phase of tetragonal and rhombohedral symmetry. The sintering temperature of piezoelectric PZT-CTC can be reduced after the addition of phosphorus without compromising the dielectric properties. The density agglomerated of 94 % of the theoretical density to been gotten for the addition of 4 wt. % of P2O5 after the agglomeration to 1050 oC. Above or below 4 wt. %, show a lower densification. Ceramics sintered at 1050 °C with 4 wt. % P2O5 achieve excellent properties, which are as follows: kp = 0.73, ρ = 0.09 × 10+4 (Ω. cm), εr = 18800, tanδ = 0.0094 and Tc = 390°C.en_US
dc.subjectDielectric propertiesen_US
dc.subjectFerroelectric propertiesen_US
dc.subjectElectronic materialsen_US
dc.subjectMethods physico-chemical of analysisen_US
dc.titleEtude des propriétés diélectriques et piézoélectriques dans le système ternaire: Pb0.98Ca0.02[(Zr0.52Ti0.48)0.98(Cr3+ 0.5, Ta5+ 0.5)0.02]O3 effet du dopageen_US
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